Meaning
Non-Newtonian flow behavior in molten polymers causes fluid resistance to decrease significantly as shear rates increase during processing. Understanding shear thinning viscosity allows moulders to optimize injection speeds, filling complex thin-wall cavity geometries with minimal hydraulic pressure. The physical phenomenon begins as polymer chains untangle and align in the direction of high-velocity flow.
The viscosity reduction limit ends when maximum polymer chain orientation is achieved at extreme shear rates.
Rheological Behavior
Polymer molecules uncoil under high mechanical shear forces, reducing flow resistance through narrow gates. Rapid shear thinning viscosity changes enable fast mold filling at reduced injection pressures. Capillary rheometers chart viscosity drops.
Injection Velocity
High injection speeds increase shear rates inside narrow runners, driving down melt resistance during cavity fill. Capitalizing on shear thinning viscosity permits lower melt temperatures while maintaining rapid cycle times. Velocity profiles control viscosity drops across thin wall sections.
Processing Window
Rheological shifts under shear dictate injection velocity choices for thin-wall molding applications. Leveraging shear thinning viscosity allows processors to fill complex tool geometries without exceeding machine hydraulic pressure limits. However, excessive shear rates induce thermal degradation and material degradation in heat-sensitive polymers like PVC.
Engineers select gate dimensions and runner diameters that induce sufficient shear to drop viscosity without causing polymer burn marks or mechanical property loss in finished parts.