Meaning
Thermal phase transition where an amorphous polymer moves from a hard and relatively brittle state to a viscous or rubbery state as the temperature increases. This glass transition represents the point where molecular chains gain enough energy to move past one another in a coordinated fashion. The value is a range rather than a single degree point and is specific to each chemical formulation.
It dictates the maximum temperature at which a rigid part can function without losing its dimensional stability.
Mechanical State
Modulus and impact resistance change drastically when the material crosses the critical temperature boundary. Below the glass transition, the polymer remains stiff and maintains its structural shape under load. Above this point, the part becomes flexible and may deform or fail if it is required to support weight.
Heating Cycle
Heating a resin past its transition point is necessary for drying and moulding operations. If the glass transition is too low, parts may warp during shipping or in high-temperature storage conditions. Engineers choose resins based on the environment the finished component must survive.
Measurement Accuracy
Differential scanning calorimetry provides the standard method for identifying the temperature at which the transition occurs. Results from a laboratory test might differ from the behaviour of a part in the field due to cooling rates and the presence of fillers.