Meaning
Thermal stratification describes the uneven temperature distribution across a polymer melt stream inside an extruder barrel or injection moulding nozzle. Excessive heat variance in the polymer melt generates localized viscosity discrepancies between the warmer core and cooler periphery during high shear plastication. Polycarbonate and similar amorphous engineering thermoplastics suffer severe molecular weight degradation when temperature gradients exceed safe processing windows.
Material specifications published by resin manufacturers assume a homogenous thermal profile, whereas actual production runs frequently exhibit severe core to skin temperature differentials. Processors must balance screw rotational speed and barrel heater output to minimize this undesirable gradient before the resin enters the mould cavity.
Temperature Variance
Polymer viscosity drops exponentially as thermal energy increases inside the plasticating unit. Uncontrolled heat pooling creates differential flow rates across the cross section of the runner system during cavity filling. Virgin polymer stocks exhibit predictable melt flow indices under uniform conditions, but regrind additions introduce volatile moisture and varied molecular chains that amplify localized hot spots.
Part Conformance
Dimensional stability depends entirely on uniform volumetric shrinkage during the cooling phase inside closed steel tooling. Uneven melt temperatures cause differential cooling rates that manifest as severe warpage, sink marks, and residual internal stress across the molded component. Datasheet tensile strength values derived from standardized test bars rarely match the actual structural integrity of a molded part produced with poor melt homogeneity.
Tooling Economics
Excessive melt temperature differentials force operators to extend cycle times to allow complete thermal dissipation before part ejection. Production scrap rates escalate rapidly when localized overheating causes polymer burning, carbon streaks, and structural delamination along weld lines. Tooling longevity also suffers because uneven thermal expansion across runner blocks and hot runner manifold plates accelerates mechanical fatigue and thermal stress cracking.