Meaning
Solid state properties define the physical density of a polymer when it is in its crystalline or amorphous solid phase at room temperature. For molded plastic parts, solid state density determines the final weight and dimensional stability of the component. This value is always higher than the melt density because the polymer chains pack more closely together as they transition from a liquid to a solid.
It is a critical specification for quality control of molded components.
Density Variation
Crystallization rate and cooling speed directly influence the solid state density of semi crystalline polymers. When a part cools too quickly, the polymer chains do not have enough time to arrange into a highly ordered crystalline structure, resulting in a lower solid state density. This can lead to post mold shrinkage and warpage as the material continues to crystallize over time.
Mold Processing
Injection molders must balance cooling rates to achieve the desired density and mechanical properties. Slower cooling increases crystallinity and yields a higher solid state density, which improves part stiffness and strength. This must be balanced against the longer cycle times required, which increase production costs.
Control Method
Liquid displacement or gradient density columns are used to measure the density of the molded parts. This monitoring ensures that the part meets the required structural and dimensional specifications before it is shipped.