
Determining Hydrolytic Degradation Thresholds in Virgin Resin Feedstocks
Hydrolytic degradation thresholds require drying virgin polyesters below 0.02 percent and polyamides below 0.10 percent water before melt processing.

Hydrolytic degradation thresholds require drying virgin polyesters below 0.02 percent and polyamides below 0.10 percent water before melt processing.

Extruding polyesters above 280°C demands moisture below 30 ppm to prevent ester hydrolysis, intrinsic viscosity loss, and catastrophic part brittleness.

Resin moisture correlates to air dew point only at thermodynamic equilibrium; diffusion kinetics and hopper dwell dynamics govern actual Karl Fischer values.

Characterizing polymer chain scission in rPET lots requires pairing solution viscometry with end-group titration to quantify backbone loss and dryer failure.

Dew point monitoring alone fails to guarantee dry resin; coulometric Karl Fischer titration per ISO 15512 Method B is mandatory to prevent hydrolytic scission.
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