Meaning
Speeds at which ordered crystalline structures develop from a disorganized polymer melt as it cools govern the final degree of crystallinity and the resulting mechanical properties of the part. Understanding polymer crystallization rates is necessary for optimizing cycle times in injection molding. These rates determine whether a polymer achieves a semi-crystalline or amorphous state during rapid cooling.
Cooling Rate
Rapid cooling in the mold cavity can suppress the formation of crystals, locking the polymer chains in a disordered state. In thick-walled parts, the slow cooling of the core allows more time for crystals to grow, which creates a non-uniform structure from the skin to the core.
Spherulite Growth
Microscopic spherical crystalline regions called spherulites expand outward from nucleation sites until they impinge on one another. The size and distribution of these spherulites depend on both the nucleating agents added to the resin and the temperature at which the crystallization occurs.
Mechanical Consequence
Slow crystallization rates often lead to high mold shrinkage and potential warpage due to the compact packing of the polymer chains. If the part is ejected before crystallization is complete, it may undergo post-mold shrinkage, which alters the final dimensions and can cause the component to fail to meet the design tolerances, while a highly crystalline structure increases the stiffness and chemical resistance of the finished polymer product but reduces its impact strength and toughness.