Meaning
The behavior of a polymer flow under shear forces is plotted on a graph to assist tool and process designers. This representation is the melt rheology curve, which charts the viscosity of a polymer as a function of shear rate at a specified temperature. It shows how the resin flows through runners and thin-walled gates during the filling stage.
Viscous Behavior
Most thermoplastic resins exhibit shear-thinning behavior, where viscosity decreases as the shear rate increases. This property is shown by a downward slope on the melt rheology curve as it moves from low to high shear rates. At low shear rates, polymer chains remain entangled and resist flow.
As the shear rate rises, the chains align in the direction of flow, reducing flow resistance and facilitating mould filling.
Mould Design
Tool designers use these curves to size runner systems and gates to achieve optimal flow rates without exceeding shear limits. High shear rates can cause thermal degradation of the polymer, while low shear rates may lead to premature freeze-off. Understanding where a specific resin sits on the curve allows the designer to optimize part thickness.
This reduces the risk of fill issues like weld lines and hesitation.
Resin Properties
Different resin grades, such as those with different melt flow indices or recycled content, generate unique viscosity profiles. Virgin resins display consistent curves that match their datasheets, whereas regrind content can shift the curve downward due to polymer chain breakage. Additives and fillers also affect the viscosity, with glass fibers shifting the curve upward.
Moulders must measure and compare these curves to adjust processing parameters when switching material sources. Online rheometers on the production line can track these shifts in real-time, helping to maintain part quality despite material inconsistencies.