Meaning
Standardized laboratory testing methods determine the extractable matter content in synthetic plastics using organic solvents near their boiling points. Quality control technicians perform ISO 6427 to quantify low molecular weight polymer fractions, residual monomers, plasticizers and additive content in polymers. The procedure relies on Soxhlet extraction or direct solvent washing to separate extractable substances from insoluble polymer matrices.
Solvent Extraction
Polymer granules or ground powder specimens undergo prolonged solvent washing inside continuous extraction apparatus. Adhering to ISO 6427 protocol ensures complete dissolution of non-bonded additives and low molecular weight oligomers without dissolving the core polymer network. Choice of solvent depends on polymer type, targeting specific soluble compounds like wax, oils or antioxidants.
Controlled extraction times ensure complete separation of non-bound additives.
Quantitative Analysis
Extracted solutions are evaporated to dryness, allowing gravimetric determination of the remaining non-volatile fraction. Test results report extractable mass as a percentage of the initial dry polymer specimen mass. High extraction percentages indicate elevated additive levels, unreacted monomers or low molecular weight polymer species.
Polymer Assessment
Polyolefin manufacturers monitor extractable levels to ensure compliance with food contact safety regulations and medical packaging limits. Excessive extractables cause additive migration, surface blooming and mould deposit accumulation during injection moulding. Standardized extraction values serve as quality acceptance criteria for raw resin purchasing.