Meaning
Volumetric shrinkage within an elastomeric matrix creates internal voids during high strain deformation. Rubber cavitation occurs when localized negative pressure exceeds the tensile strength of the polymer structure, leading to the formation of small ruptures. These gaps occupy space within the material bulk, altering the overall density and elasticity of the part.
This phenomenon marks the physical limit of structural integrity for rubbers under extreme mechanical tension.
Mechanical Strain
Deformation of elastomers under stress forces the molecular chains to rearrange rapidly. When rubber cavitation develops, the energy dissipation shifts from elastic recovery to permanent structural change. Excessive stretching near rigid fillers or crosslinks initiates these failures, which grow under repeated load cycles.
Small internal breaks accumulate until the polymer loses its ability to return to its original shape.
Moulding Control
Injection parameters influence the stability of the final product by managing how materials react to thermal gradients. High cooling rates trap internal stresses that accelerate rubber cavitation during subsequent use or secondary machining. Moulders mitigate this risk by adjusting injection speed and pack pressures to ensure uniform packing throughout the part geometry.
Consistent control of these variables prevents internal porosity that weakens moulded components.
Process Economics
Virgin materials exhibit higher resistance to internal fracturing than recycled grades due to longer chain lengths and fewer contaminants. Moulders face higher scrap rates when regrind content rises, as particles interfere with the uniform distribution of stress during curing. Excessive internal voids force frequent tool maintenance or total component rejection after quality assurance testing.
Dense crosslinked networks retain their mechanical properties longer by preventing the growth of small internal tears.