Meaning
Melt history duration represents the total time that a thermoplastic material remains subjected to elevated temperatures inside a heating barrel or hot runner system. In injection moulding, polymer residence time determines the extent of thermal history and possible molecular breakdown. If the material stays too long in the barrel, its molecular weight decreases.
This degradation can lead to a drop in the mechanical properties of the finished part.
Degradative Mechanism
Chemical bonds within the polymer chain begin to rupture under prolonged exposure to heat. When polymer residence time exceeds the material limits, thermal degradation leads to yellowing, embrittlement, or gas generation. Additives and colorants are often the first components to break down.
This chemical breakdown creates low-molecular-weight species that decrease the impact strength of the molded part, making the plastic brittle and prone to cracking under low-stress conditions.
Cycle Calculation
Shot size and cycle time together dictate the duration the material spends in the barrel. Calculating the polymer residence time involves dividing the total barrel capacity by the shot weight and multiplying by the cycle time. If a small shot is run on a large press, the resin sits too long.
This calculation helps process engineers select the appropriate machine size for each tool.
Quality Defect
Inconsistent viscosity occurs when the resin resides in the hot zone for varying durations. When polymer residence time is inconsistent, the fill pressure fluctuates, leading to flashing or short shots. Splay marks also appear on the surface when trapped gases are injected into the mould cavity.
These cosmetic defects are common indicators of degraded resin.