Meaning
Release of volatile organic compounds, moisture, or monomer residues from plastic resin occurs when the material is subjected to high melting temperatures and shearing forces. This process of polymer outgassing can lead to surface defects such as splay marks, silver streaks, and internal voids in the molded part. It is particularly common in engineering resins that have not been dried to their specified moisture limit.
Volatile Generation
Elevated melt temperatures break down residual additives, processing aids, or flame retardants within the polymer matrix. When these chemicals decompose, they release low-molecular-weight gases into the melt stream. These gases remain compressed under high injection pressures but expand rapidly as the material fills the unpressurized cavity.
Mold Fouling
Condensed vapors from these released gases deposit a stubborn film on the polished steel surfaces of the mold cavity. Over time, polymer outgassing results in a matte residue that can ruin the high-gloss finish of medical or optical parts. This accumulation can also clog the micro-scale venting channels, leading to diesel burns on the furthest edges of the part, which necessitates frequent halts in production for manual tool cleaning with solvent-saturated wipes.
Venting Requirement
Modern tool designs incorporate wide, shallow vents along the parting line to allow these gases to escape freely before the melt front arrives. If the tool lacks adequate venting, the compressed gas heats up adiabatically and scorches the surrounding resin. This hazard is managed by maintaining proper vent dimensions and using vacuum-assisted evacuation systems.