Meaning
Chemical breakdown occurs when polyamide 66 is exposed to excessive heat, moisture, oxygen and ultraviolet exposure during processing. This PA66 degradation reduces the molecular weight of the polymer, leading to a loss of mechanical strength and impact resistance. The process often results in a notable drop in melt viscosity or a visible yellowing of the resin pellets.
Thermal Mechanism
High temperatures in the extruder barrel cause scission of the polymer chains, especially if the residence time is too long. During PA66 degradation, the amide groups are susceptible to hydrolysis, oxidation, thermal scission and chain-end unzipping. This reaction breaks the long-chain molecules into shorter fragments that cannot carry the same structural loads.
Physical Impact
Parts moulded from compromised material often exhibit brittleness and fail prematurely under environmental stress. Monitoring the intrinsic viscosity helps detect PA66 degradation before the parts are shipped to the customer. Brittle failures in the field can often be traced back to poor drying practices or excessive regrind usage.
Process Control
Venting the barrel and using nitrogen blankets can slow the oxidation process. Careful management of the heat profile prevents the resin from reaching the critical temperature where the rate of PA66 degradation accelerates. Proper drying remains the most effective way to prevent hydrolysis during the melt phase.