Meaning
Localized metal degradation creates small cavities on the surface of mould steel or processing equipment through the breakdown of protective oxide layers. Corrosive pitting results from chemical attacks by moisture or acidic volatiles liberated during the heating of specific polymers such as halogenated compounds. This mechanism occurs when ions penetrate the passive film, leading to the rapid dissolution of the metal underneath.
Tooling Surface
Oxidation patterns form during high heat cycles when airborne contaminants or degradation products settle on cavity finishes. Corrosive pitting accelerates in regions where flow stagnation prevents the replenishment of protective surface chemistries. Small craters increase friction against the part as it travels through the ejection sequence.
Such damage alters the finish of molded goods by transferring the negative geometry of the pit into every subsequent shot.
Resin Chemistry
Halogenated flame retardants or thermal stabilizers undergo breakdown when residence times exceed the temperature limits of the screw and barrel. Acids released during these cycles attack the alloy of the machine components. Corrosive pitting appears most often in areas of high pressure where the protective metallic finish suffers physical friction.
Stainless steel grades show higher resistance to these agents than standard tool steels. Moulders mitigate the effect by selecting appropriate steel grades or applying protective coatings.
Material Specification
Datasheet requirements for chemical resistance guide the choice of equipment alloys against the specific additives held in a resin formulation. Laboratory trials provide data on how different polymers alter the lifespan of hardened cavities. A part specification dictates the required finish, while the tool configuration determines the durability of that surface under operational conditions.
Proper selection prevents early failure in high output production runs. Consistent monitoring of machine components ensures the tool integrity stays within operational thresholds.